This study investigates how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights for potential strategies for enhanced bioproduction. In our analysis we explore circadian regulatory rewiring of...

Lambros, E., B. Link, M. Chow, F. Lipparini, S. Hammes-Schiffer, X. Li. Assessing Implicit and Explicit Polarizable Solvation Models for Nuclear–Electronic Orbital Systems: Quantum Proton Polarization and Solvation Energetics. J. Phys. Chem. A . 2023. 127(44) 9322-9333. DOI: 10.1021/acs.jpca.3c03153...

Riechers, S. L.; X. Zhang; J. A. LaVerne, K. M. Rosso. Direct Measurement of Mineral Dissolution Enhanced by X-ray Irradiation. J Phys. Chem . C. 2023. 127 (36), 17694-17699. DOI: 10.1021acs.jpcc.3c02817 Developing a predictive understanding of mineral-phase stability in extreme chemical conditions...

Nienhuis, E. T.; Pouvreau, M.; Graham, T. R.; Prange, M. P.; Page, K.; Loring, J. S.; Stack, A. G.; Clark, A. E.; Schenter, G. K.; Rosso, K. M.; Pearce, C. I.; Wang, H.-W. Structure and reactivity of sodium aluminate complexes in alkaline solutions. J. Mol. Liq . 2022. 367(Part A), 120379. DOI: 10...

Zhao, Y.; M. Prange; M. Zong; Y. Wang; E. Walter; Y. Chen; Z. Zhu; M. H. Engelhard; X. Wang; X. Zhao; C. I. Pearce; A. Miao; Z. Wang; K. M. Rosso; X. Zhang. Understanding Trace Iron and Chromium Incorporation During Gibbsite Crystallization and Effects on Mineral Dissolution. Environ. Sci. Tech...

Graham, T. R.; Hu, J. Z.; Jaegers, N. R.; Zhang, Xin; Pearce, C. I.; Rosso, K. M. An amorphous sodium aluminate hydrate phase mediates coordination change in highly alkaline sodium hydroxide solutions. Inorg. Chem. Front . 2022. 9(24), 6344-6357. DOI: 10.1039/D2QI01642G Aluminum (Al) transformations...

Zhao, Y.; P. Chen; X. Wang; H. Hlushko; J. A. LaVerne; L. Liu; C. I. Pearce; Z. Wang; K. M. Rosso; X. Zhang. Effect of 60CO Irradiation on Boehmite Dissolution in Caustic Solutions. Environ. Sci. Tech . 2024. 58(49), 21760-21769. DOI: 10.1021/acs.est.4c07544 Here, we examine how radiation impacts...

Liu, Wei; Pouvreau, Maxime; Stack, Andrew; Yang, Xiaoning; Clark, Aurora E. Concentration Dependent Interfacial Chemistry of the NaOH(aq): Gibbsite Interface. PCCP . 2022. 24(35), 20988-21008. DOI: 10.1039/D2CP01997C Caustic conditions are often employed for dissolution of a wide variety of minerals...

Lee, J., E. Nakouzi, J. Heo, B. A. Legg, G. K. Schenter, D. Li, C. Park, H. Ma, J. Chun. Effects of particle shape and surface roughness on van der Waals interactions and coupling to dynamics in nanocrystals. J. Colloid Interface Sci . 2023. 652,1974-1983. DOI: 10.1016/j.jcis.2023.08.160 The van der...

Zhou, J.; Xue, S.; Liu, L.; Zhang, X.; Rosso, K. M. Particle-Based Crystallization. ACS Symposium Series: Crystallization via Non-Classical Pathways Vol II: Aggregation, Biomineralization, Imaging & Application. 2021 . Vol. 1383, 37-73. DOI: 10.1021/bk-2021-1383.ch002 . Particle-based...

Huestis, P.L.; Anovitz, L.M.; Kolesnikov, A.I.; Jensen, G.; Barker, J.; Bleuel, M.; Gagnon, C.; Mildner, D. F. R.; Zhang, X.; Zong, M.; LaVerne, J. A. Effects of γ-Irradiation, Cation Size and Salt Concentration on the Aggregation of Boehmite Nanoplatelets. J. Phys. Chem C . 2023. 127(10), 4896-4904...

Liu, A; Chow M.; Wildman, A.; Frisch, M. J.; Hammes-Schiffer, S.; Li, X. Simultaneous Optimization of Nuclear-Electronic Orbitals. J. Phys. Chem . A. 2022. 126(39), 7033-7039. DOI: 10.1021/acs.jpca.2c05172 Accurate modeling of important nuclear quantum effects, such as nuclear delocalization, zero...

Heo, J.; P. Butreddy; G. K. Schenter; C. J. Mundy; J. J. DeYoreo; E. Nakouzi; J. Lee; J. Chun. Colloidal phenomena reflect the interplay between interfacial solution structure, interparticle forces, and dynamical response. COCIS . 2024. DOI: 10.1016/j.cocis.2024.101887 . The physical and chemical...

Nakouzi, E.; S. Kerisit; B. A. Legg; S. Yadav; D. Li; A. G. Stack; C. J. Mundy; J. Chun; G. K. Schenter; J. J. De Yoreo. Solution Structure and Hydration Forces between Mica and Hydrophilic Versus Hydrophobic Surfaces. J. Phys. Chem C . 2023. 127 (5) 2741-2752. DOI: 10.1021/acs.jpcc.2c09120 Solid...

Lambros, E.; B. Link; M. Chow; S. Hammes-Schiffer; X. Li. Solvent Induced Proton Polarization within the Nuclear-Electronic Orbital Framework. J. Phys. Chem. Lett. 2023. 14(12), 2990-2995. DOI: 10.1021/acs.jpclett.3c00471 To explicitly account for nuclear quantum effects and solvent environments in...