This study investigates how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights for potential strategies for enhanced bioproduction. In our analysis we explore circadian regulatory rewiring of...

Guo, Q., M. Pouvreau, K. M. Rosso, A. E. Clark. Mechanisms of dissolution from gibbsite step edges elucidated by ab initio molecular dynamics with enhanced sampling. Science Direct: Geochimica et Cosmochimica Acta . 2023. 366, 201-209. DOI: 10.1016/j.gca.2023.11.007 Surface reactions underpin our...

Nakouzi, E.; S. Kerisit; B. A. Legg; S. Yadav; D. Li; A. G. Stack; C. J. Mundy; J. Chun; G. K. Schenter; J. J. De Yoreo. Solution Structure and Hydration Forces between Mica and Hydrophilic Versus Hydrophobic Surfaces. J. Phys. Chem C . 2023. 127 (5) 2741-2752. DOI: 10.1021/acs.jpcc.2c09120 Solid...

Li, S.; Lu, L.; Bhattacharyya, S.; Pearce, C. I.; Li, K.; Nienhuis,E.; Doumy, G.; Schaller, R. D.; Moeller, S.; Lin, M.-F.; Dakovski, G.; Hoffman, D.J.; Garratt, D.; Larsen, K.; Koralek, J. D.; Hampton, C. Y.; Cesar, D.; Duris, J.; Zhang, Z.; Sudar, N.; Cryan, J. P.; Marinelli, A.; Li, X.; Inhester...

Zhao, Y.; Q. Guo; S. Xue; P. Chen; Q. Zhao; L. Liu; H. Hlushko; J. LaVerne; C. Pearce; A. Miao; Z. Wang; K. M. Rosso; X. Zhang. Effect of Adsorbed Carboxylates on the Dissolution of Boehmite Nanoplates in Highly Alkaline Solutions. ES&T . 2024. 58(4): 2017-2026. DOI: 10.1021/acs.est.3c06595...

Riechers, S. L.; X. Zhang; J. A. LaVerne, K. M. Rosso. Direct Measurement of Mineral Dissolution Enhanced by X-ray Irradiation. J Phys. Chem . C. 2023. 127 (36), 17694-17699. DOI: 10.1021acs.jpcc.3c02817 Developing a predictive understanding of mineral-phase stability in extreme chemical conditions...

Smith, W.; Pouvreau, M.; Rosso, K.; Clark, A.E. pH Dependent Reactivity of Boehmite Surfaces from First-Principles Molecular Dynamics. Phys. Chem. Chem. Phys . 2022. 24(23), 14177-14186. DOI: 10.1039/D2CP00534D pH dependent interfacial chemistry depends upon the distribution and respective pKa...

Liu, L.; B. A. Legg, W. Smith, L. M. Anovitz, X. Zhang, R. Harper, C. I. Pearce, K. M. Rosso, A. G. Stack, M. Bleuel, D. F. R. Mildner, G. K. Schenter, A. E. Clark, J. J. De Yoreo, J. Chun, E. Nakouzi. Predicting Outcomes of Nanoparticle Attachment by Connecting Atomistic, Interfacial, Particle, and...

Graham, T. R.; Nienhuis, E. T.; Reynolds, J. G.; Marcial, J.; Loring, J. S.; Rosso, K. M.; Pearce, C. I. Sodium site occupancy and phosphate speciation in Natrophosphate are invariant to changes in NaF and Na3PO4 concentration. Inorg. Chem. Front . 2022. 9(19), 4864-4875. DOI: 10.1039/d2qi00868h...

Liu, T.; Nikhil, R.; Nakouzi, E.; Legg, B. A.; Chun, J.; Liu, L.; Schenter, G. K.; De Yoreo, J. J.; Anovitz, L. M.; Stack, A. G. Molecular Mechanisms of Sorbed ion Effects During Boehmite Particle Aggregation. Langmuir . 2024, 40(17), 8791-8805. DOI: 10.1021/acs.langmuir.3c03532 Classical theories...

Zhao X.; Rangel Guillen, T.; Graham, T. R.; Chen, P.; Zhao, Y.; Mergelsberg, S. T.; Zhu, Z.; Wang, Z.; Rosso, K. M.; Guo, X.; Zhang, X.; Incorporation of rare earth elements Sc, Y and La into gibbsite. J. Chem. Eng . 2024. 485:149809. DOI: 10.1016/j.cej.2024.149809 Rare earth elements (REE) are...

Pope, D. J., Prange, M. P., Clark, A. E., Rosso, K. M. Magnetic Contributions to Corundum-Eskolaite and Corundum-Hematite Phase Equilibria: a DFT Cluster Expansion Study. Am. Min . 2022. 108(6), 1109-1116. DOI: 10.2138/am-2022-8584 Magnetic contributions have the potential to significantly influence...

Kundu, S.; Hu, H.; Li, X.; Schaible, M. J.; Orlando, T. M. Electron Scattering with Ethane Adsorbed on Rare Gas Multilayers: Hole Transfer, Coulomb Decay and Ion Dissociation. J. Chem. Phys . 2023. 158(12), 124309. DOI: 10.1063/5.0099594 Positive ion desorption following electron impact dissociative...

Graham, T. R.; A. Kennedy, R. G. Felsted; R. A. Colina Ruiz; E. T. Nienhuis; K. M. Rosso, C. I. Pearce. Multinuclear PFGSTE NMR description of 39K, 23Na, 7Li, and 1H specific activation energies governing diffusion in alkali nitrite solutions. J. Magn. Reson . 2024. DOI: 10.1016/j.jmr.2024.107707...

Lambros, E.; B. Link; M. Chow; S. Hammes-Schiffer; X. Li. Solvent Induced Proton Polarization within the Nuclear-Electronic Orbital Framework. J. Phys. Chem. Lett. 2023. 14(12), 2990-2995. DOI: 10.1021/acs.jpclett.3c00471 To explicitly account for nuclear quantum effects and solvent environments in...