This study investigates how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights for potential strategies for enhanced bioproduction. In our analysis we explore circadian regulatory rewiring of...
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Hlushko H.; Ramos-Ballesteros, A.; Chen, P.; Zhang, X.; Rosso, K. M.; Pearce, C. I., LaVerne, J. A. Effect of impurities on radical formation in gibbsite radiolysis. Phys. Chem. Chem. Phys. 2024, 26(13), 9867-9870. DOI: 10.1039/d3cp06305d The generation and stabilization of gamma radiation-induced...
Zhou, J.; Xue, S.; Liu, L.; Zhang, X.; Rosso, K. M. Particle-Based Crystallization. ACS Symposium Series: Crystallization via Non-Classical Pathways Vol II: Aggregation, Biomineralization, Imaging & Application. 2021 . Vol. 1383, 37-73. DOI: 10.1021/bk-2021-1383.ch002 . Particle-based...
Lambros, E., B. Link, M. Chow, F. Lipparini, S. Hammes-Schiffer, X. Li. Assessing Implicit and Explicit Polarizable Solvation Models for Nuclear–Electronic Orbital Systems: Quantum Proton Polarization and Solvation Energetics. J. Phys. Chem. A . 2023. 127(44) 9322-9333. DOI: 10.1021/acs.jpca.3c03153...
Graham, T. R.; Hu, J. Z.; Jaegers, N. R.; Zhang, Xin; Pearce, C. I.; Rosso, K. M. An amorphous sodium aluminate hydrate phase mediates coordination change in highly alkaline sodium hydroxide solutions. Inorg. Chem. Front . 2022. 9(24), 6344-6357. DOI: 10.1039/D2QI01642G Aluminum (Al) transformations...
Liu, A; Chow M.; Wildman, A.; Frisch, M. J.; Hammes-Schiffer, S.; Li, X. Simultaneous Optimization of Nuclear-Electronic Orbitals. J. Phys. Chem . A. 2022. 126(39), 7033-7039. DOI: 10.1021/acs.jpca.2c05172 Accurate modeling of important nuclear quantum effects, such as nuclear delocalization, zero...
Li, S.; Lu, L.; Bhattacharyya, S.; Pearce, C. I.; Li, K.; Nienhuis,E.; Doumy, G.; Schaller, R. D.; Moeller, S.; Lin, M.-F.; Dakovski, G.; Hoffman, D.J.; Garratt, D.; Larsen, K.; Koralek, J. D.; Hampton, C. Y.; Cesar, D.; Duris, J.; Zhang, Z.; Sudar, N.; Cryan, J. P.; Marinelli, A.; Li, X.; Inhester...
Ho, T. A.; Rosso, K. M.; Criscenti, L. J. Atomistic Mismatch Defines Energy−Structure Relationships during Oriented Attachment of Nanoparticles. J. Phys. Chem. Lett. 2022 . 13, 9339-9347. DOI: 10.1021/acs.jpclett.2c02511 Oriented attachment is an important crystal growth pathway in nature and has...
Graham, T., Y. Wei, E. D. Walter, E. T. Nienhuis, J. Chun, G. K. Schenter, K. M. Rosso, C. I. Pearce, A. E. Clark. Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient 15N NMR spectroscopy. Chemical Communications . 2023. 59(97), 14407-14410. DOI: 10.1039...
Chen, P.; Zhu, Y.; Bergman, R.; Xue, S.; Zhao, Y.; LaVerne, J.; Guo, X.; Pearce, C. I.; Wang, Z.; Chen, T.; Rosso, K.; Zhang, X. Effects of Ionizing Radiation on the Thermodynamic Stability of Boehmite and Gibbsite. J. Phys. Chem. C . 2024. 128(8), 3578-3587. DOI: 10.1021/acs.jpcc.3c08456 We...
Wei, Y.; E. T. Nienhuis; S. T. Mergelsberg; T. R. Graham; Q. Guo, G. K. Schenter; C. I. Pearce; A.E. Clark. Cation Coordination Polyhedra Lead to Multiple Lengthscale Organization in Aqueous Electrolytes. Chem. Commun . 2023. 59 (69), 10400-10403. DOI: 10.1039/D3CC02416D Understanding multiple...
Zhao, Y.; M. Prange; M. Zong; Y. Wang; E. Walter; Y. Chen; Z. Zhu; M. H. Engelhard; X. Wang; X. Zhao; C. I. Pearce; A. Miao; Z. Wang; K. M. Rosso; X. Zhang. Understanding Trace Iron and Chromium Incorporation During Gibbsite Crystallization and Effects on Mineral Dissolution. Environ. Sci. Tech...
Reynolds, J. G.; Graham, T. R.; Pearce, C. I. Ion hydration controls self-diffusion in multicomponent aqueous electrolyte solutions of NaNO2-NaOH-H2O. Journal of Molecular Liquids . 2022. 360, 119441. DOI: 10.1016/j.molliq.2022.119441 Determining the diffusive properties of multicomponent...
Lee, J., E. Nakouzi, J. Heo, B. A. Legg, G. K. Schenter, D. Li, C. Park, H. Ma, J. Chun. Effects of particle shape and surface roughness on van der Waals interactions and coupling to dynamics in nanocrystals. J. Colloid Interface Sci . 2023. 652,1974-1983. DOI: 10.1016/j.jcis.2023.08.160 The van der...
Liu, Wei; Pouvreau, Maxime; Stack, Andrew; Yang, Xiaoning; Clark, Aurora E. Concentration Dependent Interfacial Chemistry of the NaOH(aq): Gibbsite Interface. PCCP . 2022. 24(35), 20988-21008. DOI: 10.1039/D2CP01997C Caustic conditions are often employed for dissolution of a wide variety of minerals...