This study investigates how circadian clock regulation impacts carbon partitioning between storage, growth, and product synthesis in Synechococcus elongatus PCC 7942 in providing insights for potential strategies for enhanced bioproduction. In our analysis we explore circadian regulatory rewiring of...

Nakouzi, E.; S. Kerisit; B. A. Legg; S. Yadav; D. Li; A. G. Stack; C. J. Mundy; J. Chun; G. K. Schenter; J. J. De Yoreo. Solution Structure and Hydration Forces between Mica and Hydrophilic Versus Hydrophobic Surfaces. J. Phys. Chem C . 2023. 127 (5) 2741-2752. DOI: 10.1021/acs.jpcc.2c09120 Solid...

Liu, T.; Nikhil, R.; Nakouzi, E.; Legg, B. A.; Chun, J.; Liu, L.; Schenter, G. K.; De Yoreo, J. J.; Anovitz, L. M.; Stack, A. G. Molecular Mechanisms of Sorbed ion Effects During Boehmite Particle Aggregation. Langmuir . 2024, 40(17), 8791-8805. DOI: 10.1021/acs.langmuir.3c03532 Classical theories...

Graham, T. R.; Hu, J. Z.; Jaegers, N. R.; Zhang, Xin; Pearce, C. I.; Rosso, K. M. An amorphous sodium aluminate hydrate phase mediates coordination change in highly alkaline sodium hydroxide solutions. Inorg. Chem. Front . 2022. 9(24), 6344-6357. DOI: 10.1039/D2QI01642G Aluminum (Al) transformations...

Felsted, R. G.; Graham, T. R.; Zhao, Y.; Bazak, J. D.; Nienhuis, E.; Pauzauskie, P.; Joly, A; Pearce, C.; Wang, Z.; Rosso, K. Anionic effects on concentrated aqueous lithium ion dynamics. J. Phys. Chem. Lett . 2024, 15, 5076-5087. DOI: 10.1021/acs.jpclett.4c00585 The dynamics, orientational...

Lambros, E.; B. Link; M. Chow; S. Hammes-Schiffer; X. Li. Solvent Induced Proton Polarization within the Nuclear-Electronic Orbital Framework. J. Phys. Chem. Lett. 2023. 14(12), 2990-2995. DOI: 10.1021/acs.jpclett.3c00471 To explicitly account for nuclear quantum effects and solvent environments in...

Pouvreau, M.; Q. Guo, H.-W. Wang, G.K. Schenter, C. I. Pearce, A. E. Clark, K. M. Rosso. An Efficient Reactive Force Field without Explicit Coordination Dependence for Studying Caustic Aluminum Chemistry. J. Phys. Chem. Lett . 2023. 14, 6743-6748. DOI: 10.1021/acs.jpclett.3c01176 Reactive force...

Reynolds, J. G.; Nienhuis, E. T.; Mergelsberg, S. T.; Pearce, C. I.; Rosso, K. M. The Apparent Reversal of the Law of Mass Action in Concentrated Multicomponent Aqueous Solutions. J Mol Liq . 2023. 377, 121470. DOI: 10.1016/j.molliq.2023.121470 Although it is well known that aqueous electrolyte...

Reynolds, J. G.; Graham, T. R.; Pearce, C. I. Ion hydration controls self-diffusion in multicomponent aqueous electrolyte solutions of NaNO2-NaOH-H2O. Journal of Molecular Liquids . 2022. 360, 119441. DOI: 10.1016/j.molliq.2022.119441 Determining the diffusive properties of multicomponent...

Graham, T., Y. Wei, E. D. Walter, E. T. Nienhuis, J. Chun, G. K. Schenter, K. M. Rosso, C. I. Pearce, A. E. Clark. Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient 15N NMR spectroscopy. Chemical Communications . 2023. 59(97), 14407-14410. DOI: 10.1039...

Kundu, S.; Hu, H.; Li, X.; Schaible, M. J.; Orlando, T. M. Electron Scattering with Ethane Adsorbed on Rare Gas Multilayers: Hole Transfer, Coulomb Decay and Ion Dissociation. J. Chem. Phys . 2023. 158(12), 124309. DOI: 10.1063/5.0099594 Positive ion desorption following electron impact dissociative...

Zhao X.; Rangel Guillen, T.; Graham, T. R.; Chen, P.; Zhao, Y.; Mergelsberg, S. T.; Zhu, Z.; Wang, Z.; Rosso, K. M.; Guo, X.; Zhang, X.; Incorporation of rare earth elements Sc, Y and La into gibbsite. J. Chem. Eng . 2024. 485:149809. DOI: 10.1016/j.cej.2024.149809 Rare earth elements (REE) are...

Zhang, H., Z. Wang, Y. Zhao, W. Cui, X. Zhang, S. Wang, E. D. Walter, M. J. Sassi, C. I. Pearce, S. B. Clark, K. M. Rosso. Metal Ion (Cr3+, Eu3+,UO23+) Adsorption on Gibbsite Nanoplates. Eng. Sci. 2023. 24, 896. DOI: 10.30919/es896 Gibbsite is a common and important aluminum hydroxide mineral in...

Smith, W.; Pouvreau, M.; Rosso, K.; Clark, A.E. pH Dependent Reactivity of Boehmite Surfaces from First-Principles Molecular Dynamics. Phys. Chem. Chem. Phys . 2022. 24(23), 14177-14186. DOI: 10.1039/D2CP00534D pH dependent interfacial chemistry depends upon the distribution and respective pKa...

Chen, P.; Zhu, Y.; Bergman, R.; Xue, S.; Zhao, Y.; LaVerne, J.; Guo, X.; Pearce, C. I.; Wang, Z.; Chen, T.; Rosso, K.; Zhang, X. Effects of Ionizing Radiation on the Thermodynamic Stability of Boehmite and Gibbsite. J. Phys. Chem. C . 2024. 128(8), 3578-3587. DOI: 10.1021/acs.jpcc.3c08456 We...