Journal Article
ECS Transactions, vol. 25, iss. 2, pp. 2125-2130, 2009
Authors
Olga A. Marina, Larry R. Pederson, Christopher A. Coyle, Ed C. Thomsen, Greg W. Coffey
Abstract
Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.
