Mechanistic insights into hydride transfer for catalytic hydrogenation of CO2 with cobalt complexes

Journal Article
Dalton Trans., vol. 43, iss. 31, pp. 11803-11806, 2014
Authors
N. Kumar, D. M. Camaioni, M. Dupuis, S. Raugei, A. M. Appel
Abstract

The catalytic hydrogenation of CO2 to formate by Co(dmpe)2H can proceed via direct hydride transfer or via CO2 coordination to Co followed by reductive elimination of formate.

English