Bonding trends across the series of tricarbonato-actinyl anions [(AnO2)(CO3)3]4− (An = U–Cm): the plutonium turn

Journal Article
Dalton Transactions, vol. 46, iss. 8, pp. 2542-2550, 2017
Authors
Jian-Biao Liu, Guo P. Chen, Wei Huang, David L. Clark, W. H. Eugen Schwarz, Jun Li
Abstract

Strong variation of actinide f-orbital energy-levels with nuclear AND ionic charges lowers the highest possible oxidation-states from Pu onwards.

English