Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay

Journal Article
Chemical Science, vol. 6, iss. 5, pp. 2737-2745, 2015
Authors
Jonathan M. Darmon, Neeraj Kumar, Elliott B. Hulley, Charles J. Weiss, Simone Raugei, R. Morris Bullock, Monte L. Helm
Abstract

H2 oxidation by a molecular electrocatalyst is dramatically improved by controlling proton movement from iron to the outer coordination sphere.

English