Publication - Journal Article A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media

https://doi.org/10.1039/c7cc05988d
Journal Article
Chemical Communications, vol. 53, iss. 78, pp. 10816-10819, 2017
Authors
Robert G. Surbella, Lucas C. Ducati, Kristi L. Pellegrini, Bruce K. McNamara, Jochen Autschbach, Jon M. Schwantes, Christopher L. Cahill
Abstract

A novel hydrated Pu(iii) chloride, (C5H5NBr)2[PuCl3(H2O)5]·Cl·2H2O, is prepared from aqueous media and the non-covalent interaction pairings are rationalized using electrostatic potentials.

English