Reactivity descriptors in acid catalysis: acid strength, proton affinity and host–guest interactions

Journal Article
Chemical Communications, vol. 56, iss. 54, pp. 7371-7398, 2020
Authors
Prashant Deshlahra, Enrique Iglesia
Abstract

Acid strength and proton affinity, the independent properties of catalysts and molecules, are incomplete descriptors of because cations and conjugate anions reorganize their charges as they interact as bound intermediates and transition states.

English