Publication - Journal Article Distonic radical anion species in cysteine oxidation processes

Journal Article

Physical Chemistry Chemical Physics, vol. 22, iss. 31, pp. 17554-17558, 2020

Authors

Zhengbo Qin, Gao-Lei Hou, Zheng Yang, Marat Valiev, Xue-Bin Wang

Abstract

In contrast to the first reversible oxidation step being associated with sulfinate species, a novel distonic radical anion, ^•OS–CH₂CH(NH₂)–COO⁻ has been identified with an inverted SOMO–HOMO energy order that can be restored via protonation.

Language English

Publication - Journal Article Distonic radical anion species in cysteine oxidation processes

DOI