Publication - Journal Article Putting chromium on the map for N₂ reduction: production of hydrazine and ammonia. A study of cis-M(N₂)₂ (M = Cr, Mo, W) bis(diphosphine) complexes

Journal Article

Chemical Communications, vol. 52, iss. 60, pp. 9343-9346, 2016

Authors

Jonathan D. Egbert, Molly O'Hagan, Eric S. Wiedner, R. Morris Bullock, Nicholas A. Piro, W. Scott Kassel, Michael T. Mock

Abstract

Protonolysis experiments show of the Group 6 N₂ complexes, only Cr affords N₂H₅⁺ and NH₄⁺ from reduction of the N₂ ligands.

Language English

Publication - Journal Article Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes