Journal Article
Nature Communications, vol. 12, iss. 1, 2021
Authors
Huajun Tian, Zhao Li, Guangxia Feng, Zhenzhong Yang, David Fox, Maoyu Wang, Hua Zhou, Lei Zhai, Akihiro Kushima, Yingge Du, Zhenxing Feng, Xiaonan Shan, Yang Yang
Abstract
AbstractMetal anode instability, including dendrite growth, metal corrosion, and hetero-ions interference, occurring at the electrolyte/electrode interface of aqueous batteries, are among the most critical issues hindering their widespread use in energy storage. Herein, a universal strategy is proposed to overcome the anode instability issues by rationally designing alloyed materials, using Zn-M alloys as model systems (M = Mn and other transition metals). An in-situ optical visualization coupled with finite element analysis is utilized to mimic actual electrochemical environments analogous to the actual aqueous batteries and analyze the complex electrochemical behaviors. The Zn-Mn alloy anodes achieved stability over thousands of cycles even under harsh electrochemical conditions, including testing in seawater-based aqueous electrolytes and using a high current density of 80 mA cm−2. The proposed design strategy and the in-situ visualization protocol for the observation of dendrite growth set up a new milestone in developing durable electrodes for aqueous batteries and beyond.
