Concentration-dependent ion correlations impact the electrochemical behavior of calcium battery electrolytes

Journal Article
Physical Chemistry Chemical Physics, vol. 24, iss. 2, pp. 674-686, 2022
Authors
Nathan T. Hahn, Julian Self, Darren M. Driscoll, Naveen Dandu, Kee Sung Han, Vijayakumar Murugesan, Karl T. Mueller, Larry A. Curtiss, Mahalingam Balasubramanian, Kristin A. Persson, Kevin R. Zavadil
Abstract
Emergent calcium battery electrolytes in ethereal solvents exhibit concentration-dependent ion correlations involving significant second-shell interactions. These interactions have a strong influence on both conductivity and metal cycling efficiency.
English