CO oxidation on MgAl2O4 supported Irn: activation of lattice oxygen in the subnanometer regime and emergence of nuclearity-activity volcano

Journal Article
Journal of Materials Chemistry A, vol. 10, iss. 8, pp. 4266-4278, 2022
Authors
Yubing Lu, Coogan Thompson, Chun-Te Kuo, Xiwen Zhang, Adam S. Hoffman, Alexey Boubnov, Simon R. Bare, Libor Kovarik, Hongliang Xin, Ayman M. Karim
Abstract
Ir subnanometer clusters activate surface oxygen on a traditionally non-reducible MgAl2O4 support which leads to a more active two-site mechanism during low-temperature CO oxidation.
English