Publication - Journal Article Validation of the Cossee–Arlman mechanism for propylene oligomerization on Ni/UiO-66

https://doi.org/10.1039/d3cy00570d
Journal Article
Catalysis Science & Technology, vol. 13, iss. 14, pp. 4213-4222, 2023
Authors
Benjamin Yeh, Saumil Chheda, Jian Zheng, Julian Schmid, Laura Löbbert, Ricardo Bermejo-Deval, Oliver Y. Gutiérrez, Johannes A. Lercher, Laura Gagliardi, Aditya Bhan
Abstract
Steady state rate expressions can be derived to distinguish the Cossee–Arlman and metallacycle mechanisms postulated for propylene oligomerization on nickel-based catalysts based on product selectivities.
English